Pulp, paper and paperboard. Determination of phthalates in extracts from paper and paperboard

Pulp, paper and paperboard. Determination of phthalates in extracts from paper and paperboard

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1   Scope

This European Standard specifies an analytical test method for the determination of phthalates in water, solvent and modified polyphenylene oxide (MPPO) extracts of paper and board materials and articles intended for food contact using gas chromatography coupled to mass spectrometry (GC -MS).
This method is applicable to the determination of phthalates in concentration ranging from 0,025 mg/l to 0,5 mg/l for water and solvent extracts and 0,002 mg/dm2 to 0,040 mg/dm2 for MPPO migration depending on the individual substance, the specified volume used for analysis and the value of the blank.
Table 1Phthlates determined by this method
Name
Abbreviation
Formula
CAS N°
Structure
Diisobutyl-phthalate DIBP C16H 22O4 84–69–5
tab_1
Dibutyl -phthalate DBP C16H 22O4 84–74–2
tab_2
Di-(-ethylhexyl) - phthalate DEHP C38H 24O4 117–81–7
tab_3