1 Scope
This document specifies an analytical test method for the determination of anthraquinone
(see Table 1) in water and 95 % ethanol extracts of pulp, paper and board materials and articles
intended to come into contact with foodstuffs using a gas chromatograph coupled to
a mass spectrometer (GC-MS). Moreover, acetone extracts of modified polyphenylene
oxide (MPPO) that, according to EN 14338, can be used as a simulant to assess the possible transfer/migration of substances
from paper and board into dry, non-fatty foodstuffs can be analysed with the method
presented here.
This method can be applied to determine anthraquinone in concentrations ranging from
2 µg/l to 40 µg/l in the water and solvent extracts, corresponding to 0,05 mg/kg to
1 mg/kg pulp, paper and board or, respectively, 0,1 μg/dm2 to 2 μg/dm2 in the case of migration tests with MPPO. The measurement range can be lowered by
enriching anthraquinone from the water and solvent extracts.
