Methods of analysis of wood preservatives and treated timber - Quantitative analysis of preservatives containing bis(tri-<i>n</i>-butyltin)oxide : determination of total tin

Methods of analysis of wood preservatives and treated timber - Quantitative analysis of preservatives containing bis(tri-n-butyltin)oxide : determination of total tin

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What is BS 5666-7 - Determination of total tin in wood preservative about?

BS 5666-7 discusses method of analysis of wood preservatives and treated timber. The aim of BS 5666-7 is to provide the best industrial practice to determine the reliability of the wood preservative.

BS 5666-7 is the seventh part of BS 5666 details procedures for the determination of the total tin content present in solutions and in treated wood containing bis(tri-n-butyltin) oxide. The methods have been found suitable for the determination of tin in the presence of the following:

  • Copper naphthenate
  • Dieldrin (HEOD)
  • ¾-hexachlorocyclohexane (¾-HCH, lindane)
  • Pentachlorophenyl laurate
  • Pentachlorophenol and other chlorophenols
  • 2-phenylphenol
  • Zinc naphthenate
  • Water-repellent waxes and resins

Who is BS 5666-7 - Determination of total tin in wood preservative for?

BS 5666-7 on wood preservatives is useful for: 

  • Wooden furniture manufacturers 
  • Wooden products suppliers
  • Testing laboratories 
  • Quality control personnel 

Why should you use BS 5666-7 - Determination of total tin in wood preservative?

Wood preservative solutions containing bis(tri-n-butyltin) oxide are usually formulated with technical grade material containing at least 95 % bis(tri-n-butyltin) oxide, e.g. material complying with the requirements of BS 4630. It is known that this compound can be degraded to give dibutyltin and monobutyltin compounds that will result in a decrease in fungistatic activity. It may, therefore, be necessary to determine the organotins present, but in many cases the determination of the total tin content gives adequate information.

BS 5666-7 describes a laboratory method of testing which gives a basis for the assessment of the preventive action of a wood preservative when applied as a surface treatment.  This can help to determine the fungal activity of the wood preservative that can ensure that the preservative is performing as desired.