Determination of certain substances in electrotechnical products - Hexabromocyclododecane in polymers by chromatography-mass spectrometry (GC-MS)

Determination of certain substances in electrotechnical products - Hexabromocyclododecane in polymers by chromatography-mass spectrometry (GC-MS)

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1   Scope

This part of IEC 62321 specifies two techniques for the determination of hexabromocyclododecane (HBCDD) in polymers of electrotechnical products.
The gas chromatography-mass spectrometry (GC-MS) test method is described in the normative part of this document. The GC-MS method is suitable for the determination of hexabromocyclododecane (HBCDD).
A method using high-pressure liquid chromatography-mass spectrometry (HPLC-MS) is given in informative Annex A.
These test methods have been evaluated for use with EPS (expanded polystyrene foam), XPS (extruded polystyrene foam) and ABS (acrylonitrile butadiene styrene) within the concentration ranges as specified in Table 1. The use of this method for other types of materials or concentration ranges outside those specified below has not been evaluated.
Table 1Tested concentration ranges for HBCDD by GC‑MS in various materials
Substance or element HBCDD
Parameter
Unit of measurement
mg/kg
Medium or material tested
EPS/XPS ABS
Concentration range tested 6 080 to 11 940 1 000 to 10 000
This document has the status of a horizontal standard in accordance with IEC Guide 108.